Carob

There is no evidence that carob naturally utilizes atmospheric nitrogen.

An excerpt from the article 20 facts about carob

It has been suggested that these trees, like all legumes, may form a symbiotic relationship with Rhizobium to utilize nitrogen from the atmosphere. Ongoing studies have not conclusively proven this. Some have found no root nodules, while others have found nodules containing Rhizobium bacteria. However, isotopic testing of the carob tree's tissues has not confirmed its natural use of atmospheric nitrogen.