Iguazú Falls

The first European to see Iguazu Falls was Spanish conquistador Álvar Núñez Cabeza de Vaca.

An excerpt from the article 12 facts about Iguazú Falls

It is believed to have been in 1541 when Álvar Núñez Cabeza de Vaca trekked inland from the island of Santa Catarina. A plaque was erected near the waterfall commemorating the explorer as the first European to see Iguazu.